Re-building Daniell Cell with a Li-ion exchange Film
Identifieur interne : 000130 ( Main/Exploration ); précédent : 000129; suivant : 000131Re-building Daniell Cell with a Li-ion exchange Film
Auteurs : Xiaoli Dong [République populaire de Chine] ; Yonggang Wang [République populaire de Chine] ; Yongyao Xia [République populaire de Chine]Source :
- Scientific Reports [ 2045-2322 ] ; 2014.
Abstract
Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu2+-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu2+-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg−1. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.
Url:
DOI: 10.1038/srep06916
PubMed: 25369833
PubMed Central: 4220274
Affiliations:
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<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Re-building Daniell Cell with a Li-ion exchange Film</title><author><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></titleStmt><publicationStmt><idno type="wicri:source">PMC</idno><idno type="pmid">25369833</idno><idno type="pmc">4220274</idno><idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4220274</idno><idno 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sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University</institution>, Shanghai 200433,<country>China</country></nlm:aff><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Scientific Reports</title><idno type="eISSN">2045-2322</idno><imprint><date when="2014">2014</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>Daniell cell (i.e. Zn-Cu battery) is widely used in chemistry curricula to illustrate how batteries work, although it has been supplanted in the late 19th century by more modern battery designs because of Cu<sup>2+</sup>-crossover-induced self-discharge and un-rechargeable characteristic. Herein, it is re-built by using a ceramic Li-ion exchange film to separate Cu and Zn electrodes for preventing Cu<sup>2+</sup>-crossover between two electrodes. The re-built Zn-Cu battery can be cycled for 150 times without capacity attenuation and self-discharge, and displays a theoretical energy density of 68.3 Wh kg<sup>−1</sup>. It is more important that both electrodes of the battery are renewable, reusable, low toxicity and environmentally friendly. Owing to these advantages mentioned above, the re-built Daniell cell can be considered as a promising and green stationary power source for large-scale energy storage.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Boulabiar, A" uniqKey="Boulabiar A">A. Boulabiar</name></author><author><name sortKey="Bouraoui, K" uniqKey="Bouraoui K">K. Bouraoui</name></author><author><name sortKey="Chastrette, M" uniqKey="Chastrette M">M. 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Tarascon</name></author></analytic></biblStruct></listBibl></div1></back></TEI><affiliations><list><country><li>République populaire de Chine</li></country></list><tree><country name="République populaire de Chine"><noRegion><name sortKey="Dong, Xiaoli" sort="Dong, Xiaoli" uniqKey="Dong X" first="Xiaoli" last="Dong">Xiaoli Dong</name></noRegion><name sortKey="Wang, Yonggang" sort="Wang, Yonggang" uniqKey="Wang Y" first="Yonggang" last="Wang">Yonggang Wang</name><name sortKey="Xia, Yongyao" sort="Xia, Yongyao" uniqKey="Xia Y" first="Yongyao" last="Xia">Yongyao Xia</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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